Industrial Consultancy & Sponsored Research (IC&SR) , IIT Madras

Method for Creating Nanopores in MoS2 Nanosheets by Chemical Drilling for Disinfection of Water Under Visible Light

Technology Category/Market

Categories: Micro & Nano Technology, Environmental Engineering

Industry: Water Treatment & Desalination Industry, Environmental Technology, Chemical Engineering, Nanotechnology, Catalysis, Renewable Energy, Biotechnology & Medical Industry, Pharmaceutical, Cosmetics & Personal Care Industries.

Applications: Water Desalination & Disinfection, Sensors, Energy Storage, Photocatalysis, Anti-bacterial Applications, Environmental Remediation, Advanced Materials, Nano-filtration.

Market: The global market for Ultraviolet (UV) Disinfection estimated at US $ 4.7 B in 2022, is projected to reach a revised size of US $ 12.9 B by 2030, growing at 13.4% CAGR in 2022-2030.

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Problem Statement

  • Water scarcity is a global concern, and finding efficient methods for water purification and disinfection is crucial.
  • Traditional disinfection methods often involve use of chemicals or UV light, which can have many drawbacks and in some cases it can make the water harmful for consuming.
  • Old methods could not be adapted for large-scale industrial applications. The scalability is important for addressing real-world water treatment challenges, as large volumes of water need to be treated efficiently.
  • Existing methods for introducing nanopores in MoS2 nanosheets often involve complex and sophisticated instrumentation, making them expensive and difficult to scale up.
  • Thus, an invention is needed to address challenges in water treatment, that offers a simpler & more cost-effective method for introducing nanopores in MoS2 nanosheets, contribute to advancements in nanomaterials, and potentially provide more environmentally friendly water disinfection way.

The present patent discloses a method that addresses above mentioned issues.

Technology

The present Patent discloses a method of making nanoscale holes in a two dimensional MoS2 nanosheets, the method comprising:

  • Electrospray deposition (under ambient conditions) of reactive Ag+ ions onto a 2D MoS2 nanosheets, wherein the Ag+ ions react with the sulfur atoms on the basal plane of MoS2 nanosheets forming Ag2S, resulting in a defect-rich MoS2 nanosheets

Wherein

  • The Mo rich edges of the said nanoscale holes in MoS2 nanosheet generates H2O2 under visible light for disinfection of water efficiently.
  • Ag+ ions are selected from various salts of Ag including but not limited to silver acetate, silver nitrate, and silver perchlorate.
  • Chemical drilling with metal ions make MoS2 nanosheet photocatalytically active, which increases reactive oxygen species generation
  • The nanoporous MoS2 nanosheets supported on silica, alumina is used as a device for filtration and as a membrane for desalination of water.
  • The metal ions for chemical etching are supplied as droplets in the gas phase onto the 2D nanosheets supported on a substrate.

Key Features/Value Proposition

Enhanced Water Interaction:

  • Nanopores in MoS2 nanosheets increase surface area and reactivity.
  • This boosts efficiency in water treatment by improving interactions with water molecules.

Improved Contaminant Removal:  

  • Defect-rich nanoporous structure enhances surface reactivity. This aids in removing contaminants from water, making it cleaner. The result showed 100% disinfection after 5 cycles (Refer Fig 3).

Controlled Nanopore Formation:  

  • Electrosprayed Ag ions create controlled nanopores in nanosheets. Adjusting deposition time customizes pore sizes for various applications.

Versatile Applications:

  • Customizable nanopore size suits diverse industrial needs like in catalysis, sensing, and energy storage, beyond water treatment.

Sustainable Water Disinfection:  

  • Using visible light aligns with sustainable practices.
  • Disinfection method meets environmental regulations and benefits nature and health.

Relevance to Industry Challenges:

  • Addressing water scarcity and pollution aligns with industry challenges. The technology’s potential solutions make it more significant.

Industrial Feasibility:  

  • Process’s efficiency holds industrial promise.
  • Scalability makes it suitable for large-scale water treatment.

Cost-Effectiveness and Simplicity:  

  • Affordability and simplicity benefit industrial adoption. The process is cost-effective, easy, and works in regular temperatures.

Refer Fig 1, 2, and 3

Questions about this Technology?

Contact for Licensing

Research Lab

Prof. Pradeep T

Department of Chemistry

Intellectual Property

  • IITM IDF No: 1589

  • IP Grant No: 356015

Technology Readiness Level

TRL-4

Technology Validated in Lab

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