Industrial Consultancy & Sponsored Research (IC&SR) , IIT Madras

A Chromium Oxynitride Electrochemical Storage Device and a Chromium Oxynitride Nanoparticle Electrode

Categories for this Invention

Technology: A Chromium Oxynitride Nanoparticle electrode used in  supercapacitor.

Category: Micro & Nano Technologies/ Chemistry & Chemical Analysis/ Electronics & Circuits.

Industry: Metallurgical/Chemical /Energy.

Application: Advanced Materials, Clean Energy

Market: The global market size of nanoparticles is estimated to grow from USD 5.1 billion in 2023 to USD 15.1 billion by 2035, representing a CAGR of 9.4% during the forecast period 2023-2035.

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Problem Statement

  • Researchers are studying metallic nitrides, specifically chromium nitride and chromium oxynitride, due to their electrical, optical, mechanical, and tribological properties.
  • These materials are used in anti-wear and corrosion films due to their high hardness and resistance.
  • Chromium nitride is also used in electrochemical energy storage, particularly as a super capacitor.
  • Super capacitors have high capacitance, making them faster to store electricity than batteries.
  • They store charge through two main  mechanisms: electrical double layer (EDL) capacitance and pseudo capacitance.
  • Nano-structuring strategies are being explored to enhance electrochemical energy storage and catalytic applications.

Technology

A Chromium Oxynitride electrochemical storage device/ Chromium Oxynitride nanoparticle electrode consists of a

  • Positive Electrode,
  • Negative Electrode, and
  • Separator, coated with chromium oxynitride nanoparticles on a charge substrate acting as a current collector.
  • Separator comprises an anion exchange membrane.
  • The charge substrate is one of, selected from nickel foam, carbon paper, carbon cloth, stainless steel, glassy carbon, titanium foil and copper foil.

Key Features / Value Proposition

Device is used as a super capacitor with

  • High cyclic stability
  • 10000-15000 cycles
  • Excellent capacitance retention
    (95-99%.)

supercapacitor is fabricated structure

  • coin cell supercapacitor of 17-20mm diameter.
  1. Maintains 92-98% of specific capacitance even at high current densities exceeding
    2
    A g-1.
  2. Excellent charge storage capability.
  3. It has a specific capacitance ranging from

  • 140-150 Fg-1 at a scan rate 5 mV s-1 and
  • 80-90 F g-1 at a scan rate 500 mV s-1.
  1. Generating a photocurrent of
    30-40
    mA cm-1 in 1M KOH medium Under light illumination of 300W Xenon lamp for a period of 3h.
  2. Generating a current of
    65-75 mA cm-2 at 5 mV s-1 when dispersed in a suitable medium.

Questions about this Technology?

Contact For Licensing

sm-marketing@imail.iitm.ac.in
ipoffice2@iitm.ac.in

Research Lab

Prof. Tiju Thomas

Department of Metallurgical and Materials Engineering

Intellectual Property

  • IITM IDF Ref. 1948
  • Patent No: IN 534594

Technology Readiness Level

TRL 4

Technology Validated in Lab

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